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硝胺/高氯酸铵/丁羟推进剂高压燃烧特性
鲁国林
湖北航天化学技术研究所 湖北襄樊441003
摘要:
研究了低铝含量(5%)的NA(硝胺)/AP/HTPB推进剂高压(15MPa~22MPa)燃烧特性。结果表明:二茂铁衍生物(RMT)能大幅提高推进剂燃速和降低高压燃速压强指数。随着RDX含量(15%~35%)增加,推进剂燃速基本不变;而HMX(15%~30%)含量增加,燃速呈降低趋势。提高配方中RMT含量、细AP的含量或采用RMT/铬酸盐组合催化剂的方法都可将NA/AP/HTPB推进剂高压压强指数降低到0 45以下。
关键词:  端羟基聚丁二烯推进剂  硝胺推进剂  推进剂燃速  燃烧性能
DOI:
分类号:V512
基金项目:九五国家重大跨行业预研课题 (1 2 0 60 3 3 41 1 7)。
Combustion property of Nitramine/AP/HTPB propellant under high pressures
LU Guo-lin
Hubei Inst. of Aerospace Chemotechnology, Xiangfan 441003, China
Abstract:
The combustion property of Nitramine (NA)/AP/HTPB propellant containing aluminium (5%) is investigated under high pressures (15MPa~22MPa). The results show that ferrocene derivant (RMT) can effectively enhance burn rate of propellants and reduce its pressure exponent under high pressures; The propellant burn rates maintain constant with raising the content of RDX; But burn rates of HMX propellant decrease. The pressure exponent of NA/AP/HTPB propellant is reduced to 0.45 under high pressures by means of raising the content of RMT, the fine particle AP or using RMT/chromic acid salt composite catalysts.
Key words:  Hydroxy terminated polybutadiene propellant  Nitramine propellant  Propellant burning rate  Combustion property