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NEPE推进剂的热分解(Ⅰ)粘合剂的热分解
赵凤起, 李上文, 汪渊, 潘清, 袁潮, 罗阳
西安近代化学研究所 陕西西安710065
摘要:
利用快速热裂解原位反应池 (气体原位反应池 ) /快速扫描傅里叶变换红外光谱 (RSFT IR)和固体原位反应池 /RSFT IR联用装置 ,实时测定了NEPE推进剂粘合剂气相及凝聚相热裂解产物 ,研究获得了在线性升温条件下NEPE推进剂粘合剂的热分解特征 ,并讨论了其热分解机理。
关键词:  聚醚推进剂  推进剂粘合剂  含能增塑剂  热分解
DOI:
分类号:V512.3
基金项目:
Study on the thermal decomposition of NEPE propellant (Ⅰ)Thermal decomposition of binder
ZHAO Feng qi, LI Shang wen, WANG Yuan, PAN Qing, YUAN Chao, LUO Yang
Xi’an Modern Chemistry Research Inst , Xi’an 710065,China
Abstract:
Two simultaneous devices of the fast thermlysis reaction cell (gas reaction cell ) in situ in conjunction with rapid scan fourier transform infrared spectroscopy (RSFT IR), were the solid reaction cell in situ /RSFT IR are used to measure the gas products and condensed phase products of the thermal decomposition of the NEPE propellant binder in real time Under Linear temperature increase condition, the thermal decomposition characteristics of NEPE propellant binder was studied On the basis of the results obtained, the thermal decomposition mechanism was discussed
Key words:  Polyether propellant  Propellant binder  Energetic ptasticizer  Thermal decomposition