| 摘要: |
| 通过玻璃化转变温度和表观活化能以及由ＶＦＴ方程导得ＷＬＦ方程粘弹系数的两种新计算方法。用该方法分别计算１０个体系的粘弹系数，结果表明，用ＤＳＣ技术可以获得ＷＬＦ方程，３种计算方法获得的粘弹系数符合较好。 |
| 关键词: 高能材料 粘弹性 活化能 转变温度 |
| DOI： |
| 分类号:V511.1 |
| 基金项目: |
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| TWO METHODS USED TO CALCULATE WLF EQUATION OF LOW TEMPERATURE RELAXATION FOR ENERGETIC MATERIALS |
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Liu Ziru, Qin Yaping, Kong Yanghui, Yin Cuimei, Luo Yang
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Xi’an Modern Chemical Research Inst.,Xi’an,710065
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| Abstract: |
| Two methods which were derived from the temperature and apparent activation energy at glass transition and from VFT equation were used to calculate the viscoelastic coefficients in WLF equation.The viscoelastic coefficients of ten systems were calculated with the two methods respectively.The results show that the WLF equation can be obtained by DSC,and the viscoelastic coefficients obtained from three methods are in good agreement |
| Key words: Energetic material Viscoelasticity Activation energy Transition temperature |
