| 摘要: |
| 一甲肼是一种重要的液体推进剂，分离反应过程所生成的水是确保一甲肼质量的关键。测定了甲基肼－水（ＭＭＨ－Ｈ２Ｏ）物系在１０１．３３ｋＰａ下的汽液平衡，以及电解质对其汽液平衡的影响。采用盐效应和溶剂化的方法，研究了不同电解质对ＭＭＨ－Ｈ２Ｏ汽液平衡的盐效应。 |
| 关键词: 甲基肼 汽液平衡 盐效应 |
| DOI： |
| 分类号:V511 |
| 基金项目:国家化学工程联合实验室开放基金资助项目 |
|
| STUDIES ON VAPOR LIQUID EQUILIBRIUM OF MONOMETHYLHYDRAZINE WATER BINARY SYSTEM |
|
Mi Zhengtao Li Deqing Qiu LiqinDept.of Chemical Engineering1, Tianjin Univ.1, Tianjin1, Zhou Jiyi2
|
|
1.Dept.of Chemical Engineering,Tianjin Univ.,Tianjin,300072;2.Liming Chemical Research Inst.,Luoyang,47100
|
| Abstract: |
| Monomethylhydrazine(MMH)is an important liquid propellant.The water produced in the process of separation and reaction is critical for the quality of MMH.The vapor liquid equilibrium(VLE)of MMH H 2O binary system was measured under 101 3kPa and the influence of the MMH H 2O electrolyte ternary systems was considered.Electrolyte remarkably raised the volatility of MMH and changed the VLE of MMH H 2O binary system.The VLE of MMH H 2O NaCl and MMH H 2O NaOH ternary systems were studied by experiments.Salt effects of electrolytes were correlated with salt effect coeffecient method and solvation method.NaOH had greater effect on MMH H 2O binary system than NaCl.Salt effects of these two electrolytes were compared |
| Key words: Monomethylhydrazine Vapor liquid equilibrium + Salt effect + |
