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两种新型含铜催化剂对RDX/AP催化热分解的研究
陈力1, 龚华1, 刘训恩1, 唐松青1, 田德余2, 朱慧2, 曾志成2, 徐文英2
1.中国科学院上海有机化学研究所;2.国防科技大学材料科学与应用化学系
摘要:
通过热分解试验,系统地研究了两种新型含铜催化剂对RDX,AP,RDX/AP的催化作用,由热分析图谱及动力学计算结果可以看出:YB对AP,QC对RDX及YB+QC对RDX/AP的热分解有明显的催化作用,其推进剂的燃速测定结果也进一步证明其催化效果。
关键词:  燃烧催化剂  热分解  催化  硝胺推进剂
DOI:
分类号:V512
基金项目:
A RESEARCH ON CATALYTIC THERMAL DECOMPOSITION OF RDX/AP BY TWO COPPER-CONTAINING CATALYSTS
Chen Li1, Gong Hua1, Liu Xunen1, Tang Songqing1, Tian Deyu2, Zhu Hui2, Zeng Zhicheng2, Xu Wengying2
1.Shanghai Inst.of Organic Chemistry,Chinese Academy of Sciences, Shanghai. 200032;2.Depart. of Material Science and Applied Chemistry,National Univ. of Defense Techno
Abstract:
This paper describes the catalytic effect of two copper-containing catalysts on the thermal decomposition of RDX, AP and RDX/AP. The thermal analysis figures and the dynamic computation show that YB, QC and YB+QC have obviously catalytic effects on AP, RDX and RDX/AP respectively. The burning rates of propellants containing YB, QC and YB+QC respectively also show their catalytic effects.
Key words:  Combustion Catalyst  Thermal Decomposition  Catalysis  Nitramine Propellant